Naming Carboxylic Acids
(Chemical) Definition of Carboxylic Acids:
Carboxylic Acids are organic chemical compounds that include:
- a -carbonyl group (i.e. an oxygen atom attached to a carbon atom by a double covalent bond)
and
- a -hydroxyl group (i.e. an oxygen atom attached to a carbon atom by a single covalent bond and a hydrogen attached to the same oxygen atom by another single covalent bond)
... both
attached to the same carbon atom.
Due to carbon having a valancy of 4, the carbon atom to which these two functional groups are attached must always be located at the end of a chain of carbon atoms, the length of the chain varying from one (carbon atom) upwards:
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Carboxylic Acid molecules can vary in size up to very long molecules most of which consist of carbon atoms attached to each other and also to hydrogen atoms. |
Names of Carboxylic Acids in General
Carboxylic Acids are named according to the same system as other organic compounds, with the suffix -oic acid used to indicate that both a carbonyl group and a hydroxyl group are both attached to the same carbon atom, which is located at the end of a chain or branch of carbon atoms forming the molecule (except in the case of methanoic acid, which includes only one carbon atom).
The first step to consider when working out the name of a carboxylic acid molecule is the number of carbon atoms forming a chain. If they are attached together in a linear (i.e. unbranched) configuration then the number of carbon atoms is indicated according to the same system as used for naming alkanes.
However, if the carbon atoms do not form a simple linear chain, but include branches, the longest linear chain of carbon atoms within the molecule determines the base of the name of the compound, onto which is added information about the branches incl. their lengths in terms of the number of carbon atoms in each branch (i.e. methyl- usually indicates a branch consisting of just one carbon atom attached to the main chain, ethyl- indicates a branch of two carbon atoms in length, etc.) and their positions along the longest linear carbon chain (e.g. attached to the 2nd carbon, 3rd carbon, etc.).
The simplest linear caboxylic acids are named and their structures drawn in the following table.
More complex alcohol molecules follow afterwards.
Names and Structures of simple Linear Carboxylic Acids
The homologous series of linear carboxylic acids is shown below.
Number carbons in chain |
Name |
Simple Structure |
Other Names = Synonyns
(*Examples not complete lists) |
and simple formula |
showing bond types but not accurate bond angles |
 |
1 |
|
 |
- methanoic acid
- formylic acid
- aminic acid
- hydrogen carboxylic acid
- formira
and others.
|
2 |
|
 |
- acetic acid
- ethylic acid
- vinegar acid
- methanecarboxylic acid
and others.
|
3 |
|
 |
- propionic acid
- ethylformic acid
- metacetonic acid
- methylacetic acid
- pseudoacetic acid
- methyl acetic acid
- ethanecarboxylic acid
- carboxyethane
and others.
|
4 |
|
 |
- n-butanoic acid
- butyric acid
- n-butyric acid
- 1-butyric acid
- butanic acid
- propylformic acid
- butanic acid
- ethylacetic acid
- 1-propanecarboxylic acid
- butoic acid
and others.
|
5 |
|
 |
- n-pentanoic acid
- valeric acid
- n-valeric acid
- valerianic acid
- 1-butanecarboxylic acid
- propylacetic acid
- butanecarboxylic acid
- pentoic acid
and others.
|
6 |
|
 |
- n-hexanoic acid
- caproic acid
- n-caproic acid
- capronic acid
- hexoic acid
- butylacetic acid
- pentiformic acid
- n-hexylic acid
- n-hexoic acid
- pentylformic acid
- 1-pentanecarboxylic acid
and others.
|
|
|
7 |
|
 |
- n-heptanoic acid
- enanthic acid
- oenanthic acid
- enanthylic acid
- n-heptylic acid
- n-heptoic acid
- heptoic acid
- heptylic acid
- 1-hexanecarboxylic acid
- hexacid C-7
and others.
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8 |
|
 |
- n-octanoic acid
- caprylic acid
- n-caprylic acid
- octylic acid
- n-octylic acid
- octoic acid
- n-octoic acid
- 1-heptanecarboxylic acid
- enantic acid
- octic acid
- hexacid C-8
and others.
|
9 |
|
 |
- n-nonanoic acid
- pelargonic acid
- nonylic acid
- pelargic acid
- nonoic acid
- n-nonylic acid
- n-nonoic acid
- 1-octanecarboxylic acid
- hexacid C-9
and others.
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10 |
decanoic acid (C10H20O2) |
 |
|
 |
- n-decanoic acid
- capric acid
- n-capric acid
- decylic acid
- caprinic acid
- decoic acid
- n-decylic acid
- n-decoic acid
- caprynic acid
- 1-nonanecarboxylic acid
- C10 fatty acid
and others.
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Why stop at ten carbon atoms (in the chain) ? It doesn't, there are more similar linear carboxylic acids. We stopped here due to page width. |
Important Note: *The synonyms indicated for compounds listed above are just some examples of alternative names found online and believed to have been used to refer to the substance indicated. They have not all been verified and may include common (non-scientific) names, trade names specific to particular suppliers, and perhaps errors. The purpose of these lists is to give a general indication of the range of names by which carboxylic acids are known - both generally, and specifically.
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Note:
This is one of many pages about types of organic compounds in our Organic Chemistry Section. Similar and related pages describe hydrocarbons, alkanes, haloalkanes, alkenes, alkynes, cycloalkanes, aromatic hydrocarbons (arenes), alcohols, esters, ethers, aldehydes, ketones, carboxylic acids, acid chlorides, acid anhydrides, azo dyes, amines, amides, nitriles, amino acids (chemistry), peptides, proteins (chemistry), polypeptides and others. If you need further information ask your chemistry tutor.
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